Overview of Electrolytic Organic Destruction (EOD) Applications

This page discusses applications of EOD technology.  EOD technology removes organics
from aqueous streams using electrochemical and chemical oxidation (
click here for more
information on the EOD Process).    For additional information on EOD including systems,
services and economics, simply click on the word or follow the link on the navigation bar to
Products and Services.

Test Results

The links below show results from testing of EOD in various applications at different scales:


General Application Information

The discharge of organic waste into surface water or deep wells is encountering increased
regulatory restrictions (BOD, COD, and others). In addition, even though discharges may
meet regulatory limits, there is often additional justification for reducing such discharges,
for example:

  • Improve the public image of a company by reducing discharges of pollutants such
    as those found on the Toxic Release Inventory List.
  • Meet Sustainable Development Objectives
  • Reduce EPA documentation requirements.
  • Avoid the high present-day cost of drilling and maintaining deep wells and avoid
    concerns about future liability.
  • Recover and recycle valuable resources.
  • Alleviate the tendency for organic contaminants to accumulate, thus affecting the
    efficiency and effectiveness of chemical processes and, in some instances,
    accelerating corrosion in closed-loop systems.

Electrochemical oxidation has been shown to be feasible for many organic contaminants.
S. Stucki reported laboratory results for many organic compounds using an
electrochemical oxidation index  (Journal of Applied Electrochemistry 21 (1991) 99-104,
Electrochemical Waste Water Treatment using High Overvoltage Anodes, Part II: Anode
Performance and Applications, S. Stucki et al) .

This index is the oxygen produced in the presence of an organic divided by the oxygen
produced without the organic. It measures the portion of electrons that oxidize the
organic.   The following table shows the electrochemical oxidation index (EOI) for a
number of organic compounds:
Organic Compound
EOI
Organic Compound
EOI
Ethanol
0.49
Phenol
0.60
Acetone
0.21
Aniline
0.43
Acetic Acid
0.09
Benzenesulfonic Acid
0.28
Formic Acid
0.05
5-methyl-3-Aminoisoxalzole
0.25
Tartaric Acid
0.34
Orange II
0.58
Oxalic Acid
0.05
Antrachinon Sulphonic Acid
0.18
Malonic Acid
0.21
Nitrobenzene
0.80
Meleic Acid
0.21
Nitrobenzenesulphonic Acid
0.46
Benzoic Acid
0.79
Triaminotriazin
0.02
Naphtalene-2-Sulphonic Acid
0.51
EDTA
0.30
Naphtalene-1-Sulphonic Acid
0.41
p-NDMA
0.37
4-Chlorphenol
0.35
 
 
EOD can provide an alternative method for organic removal versus biological treatment
methods.  This is true where the organic compounds are especially toxic, not treatable
by biological organisms (biorefractory) or require a very long time to be broken down by
bacteria.  EOD systems can be used as a primary treatment technique or as a
complement to a biological system by converting organic compounds to forms that are
more treatable by bacteria.

EOD is also an alternative method for organic removal versus adsorption techniques
such as activated carbon where the disposal or regeneration of the adsorbent is
expensive or creates future environmental liability.  It is often less expensive than
evaporation and incineration. It can also enhance reverse osmosis and ultrafiltration
processes.

EOD systems and technology offered by Spartan Environmental have been
demonstrated for different chemical substrates on the commercial, pilot and laboratory
scale.  Click on the links at the top of the page to learn about specific examples where
EOD technology has been demonstrated.
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